Formation of a dihydroborole by catalytic isomerization of a divinylborane.

نویسندگان

  • Raúl A Adler Yañez
  • Gerald Kehr
  • Constantin G Daniliuc
  • Birgitta Schirmer
  • Gerhard Erker
چکیده

Diphenylamino(divinyl)borane (1a) adds two molar equivalents of Piers' borane [HB(C6F5)2] to give the expected double hydroboration product. In contrast diisopropylamino(divinyl)borane (1b) reacts cleanly already with one molar equivalent of HB(C6F5)2 to give the α-borylated tetrahydroborole derivative 10 in good yield. Subsequent treatment of 10 with benzaldehyde proceeded by retro-hydroboration to give the hydroboration product of the aldehyde plus the dihydroborole 3b. We were able to achieve the divinylborane to dihydroborole isomerization (1b to 3b) catalytically: treatment of diisopropylamino(divinyl)borane (1b) with 15 mol% of Piers' borane at elevated temperature gave (diisopropylamino)dihydroborole 3b in good yield.

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عنوان ژورنال:
  • Dalton transactions

دوره 43 28  شماره 

صفحات  -

تاریخ انتشار 2014